Analyse of structural and electrical properties of NaBa((2-x))Nd-2x/3Nb5O15 solid solution with (0 < x <1) - Université de Picardie Jules Verne Accéder directement au contenu
Article Dans Une Revue Materials Chemistry and Physics Année : 2022

Analyse of structural and electrical properties of NaBa((2-x))Nd-2x/3Nb5O15 solid solution with (0 < x <1)

Résumé

The structural and electrical properties of NaBa(2-x)Nd2x/3Nb5O15 ceramics were reported. All samples were prepared by the conventional solid-state reaction. A Room temperature X-ray study has allowed identifying the stabilization of tetragonal Tungsten Bronzes (TTB) structure with P4bm as space group for low Nd3+ concentration, whereas a centrosymmetric space group P4/mbm has been revealed for the high concentration. The dielectric study carried out on the prepared ceramics showed that the studied system undergo a behavior change from normal ferroelectric to a relaxor one with the increasing Neodymium amount. The complex impedance spectroscopy highlighted a thermally activated relaxation process in our samples. A short-range relaxation is proposed for x = 0.3 sample, while a possible coexistence of both localized and long-range relaxation for x = 1. Further, the Nyquist plot of the impedance is given for the low and higher Nd3+ samples and a simple model is proposed to fit the results.
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hal-03608398 , version 1 (05-01-2024)

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Paternité - Pas d'utilisation commerciale

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M. Belarbi, Manal Benyoussef, Y. Tamraoui, B. Manoun, A. Cantaluppi, et al.. Analyse of structural and electrical properties of NaBa((2-x))Nd-2x/3Nb5O15 solid solution with (0 < x <1). Materials Chemistry and Physics, 2022, 277, ⟨10.1016/j.matchemphys.2021.125513⟩. ⟨hal-03608398⟩
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